

Adipic acid, or more formally hexanedioic acid, is a white crystalline solid that melts at 152 潞C. It is one of the most important monomers in the polymer industry.
Adipic acid is found in beet juice, but the article of commerce鈥斺増2.5 million tonnes of it per year鈥攊s manufactured. In 1906, French chemists L. Bouveault and R. Locquin reported that adipic acid can be produced by oxidizing cyclohexanol. Today, the most common manufacturing process is the nitric acid (HNO3) oxidation of a cyclohexanol鈥揷yclohexanone mixture called KA (for ketone鈥揳lcohol) oil.
Almost all adipic acid is used as a comonomer with hexamethylenediamine to produce nylon 6-6. It is also used to manufacture other polymers such as polyurethanes.
Using HNO3聽to produce adipic acid has its downside: Copious amounts of nitrous oxide (N2O), a greenhouse gas, are coproduced and released into the atmosphere. In late 2014, K. C. Hwang and A. Sagadevan of National Tsing Hua University (Hsinchu City, Taiwan) reported聽. This method eliminates the production of N2O; but before the process can be used commercially, problems associated with the formation of organic peroxides from ozone and the difficulty of using UV light on a large scale must be overcome.

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