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Malic acid, a hydroxydicarboxylic acid, is found in all forms of life. It exists naturally only as the L-enantiomer. It should not be confused with the similar sounding maleic听 and malonic听补肠颈诲蝉.
L-Malic acid gives many fruits, particularly apples, their characteristic flavor. It is often referred to as 鈥渁pple acid鈥�. The word malic is derived from the Latin m膩lum, for which Malus, the genus that contains all apple species, is also named.
The global market size for malic acid (natural and manufactured1) is 鈮圲S$200 million; the US market is 鈮�$35 million. The primary end use in the United States is for flavoring beverages, foods, and confectionaries, with much smaller quantities used in cosmetics and personal care products. The price of malic acid ranges from US$0.90 to $10.00/kg, depending on the purity, quantity, and end use.
1. The manufactured product is racemic.
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L-Malic acid hazard information*
Hazard class** | Hazard statement | |
---|---|---|
Skin corrosion/irritation, category 2 | H315鈥擟auses skin irritation | ![]() |
Serious eye damage/eye irritation, category 2A | H319鈥擟auses serious eye irritation | ![]() |
Specific target organ toxicity, single exposure, respiratory tract irritation, category 3 | H335鈥擬ay cause respiratory irritation | ![]() |
* Compilation of three safety data sheets.
** Globally Harmonized System of Classification and Labeling of Chemicals.
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L-Malic acid fast facts
CAS Reg. No. | 97-67-6 |
nomenclature | Butanedioic acid, 2-hydroxy-, (2S)- |
Empirical formula | C4H6O5 |
Molar mass | 134.09 g/mol |
Appearance | White crystalline powder, granules, or needles |
Melting Point | 130 潞C |
Water solubility听 | 558 g/L |

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