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All organic chemists (and many others) know coronene as a highly symmetrical polycyclic aromatic hydrocarbon. It鈥檚 quite a useful compound, and a group of European chemists decided to increase its utility by adding sulfur atoms all around its periphery.

Klaus Mu虉llen, Xinliang Feng, and 10 coauthors at the Technical University of Dresden (Germany), the Max Planck Institute for Polymer Research (Mainz, Germany), and the Polytechnic University of Milan (Italy), . (Nomenclature purists will insist on calling it coroneno[1,12-cd:2,3-c鈥�d鈥�:4,5-c鈥�d鈥�:6,7-c鈥磀鈥�:8,9-c鈥粹赌�d鈥粹赌�:10,11-c鈥粹赌�d鈥粹赌砞hexakis[1,2]dithiole.)

Beginning with coronene, the researchers produced the persulfurated compound in four steps:

• chlorinating with AlCl₃/ICl;
• thiobenzylating with benzyl mercaptan and base;
• displacing the benzyl groups with lithium; and
• removing the lithium atoms with acid under oxidizing conditions to form disulfide linkages.

The authors proceeded to obtain physical and spectral properties of their product, which they call a 鈥渟ulflower鈥�. Because of the compound鈥檚 low solubility in common organic solvents, however, they were unable to obtain an NMR spectrum or to grow single crystals. Despite these difficulties, they determined that the entire molecule is symmetrically hexagonal and coplanar.

Persulfurated coronene isn鈥檛 just a laboratory curiosity. The authors postulated that because of its high sulfur content and favorable redox behavior, their sulflower could work well in cathodes for lithium鈥搒ulfur batteries. Experimentation bore this out: Initial discharge and charge capacities of 424 and 496 mAh/g, respectively, reflected a high coulombic efficiency of 85%. This and other results showed that the performance of the new molecule compares favorably with other sulfur-based materials.

In December, C&EN named persulfurated coronene as one of its .