FOR IMMEDIATE RELEASE
ACS News Service Weekly PressPac: January 27, 2021
A mild way to upcycle plastics used in bottles into fuel and other high-value products Â
JACS Au
Plastic is ubiquitous in people’s lives. Yet, when plastic-containing items have fulfilled their missions, only a small amount is recycled into new products, which are often of lower quality compared to the original material. And, transforming this waste into high-value chemicals requires substantial energy. Now, researchers reporting in ACS’Â�JACS Au have combined a ruthenium-carbon catalyst and mild, lower-energy reaction conditions to convert plastics used in bottles and other packaging into fuels and chemical feedstock.Â
Global production of sturdy, single-use plastic for toys, sterile medical packaging, and food and beverage containers is increasing. Polyolefin polymers, such as polyethylene and polypropylene, are the most common plastics used in these products because the polymers� molecular structures � long, straight chains of carbon and hydrogen atoms � make materials very durable. It’s difficult to degrade the carbon-to-carbon bonds in polyolefins, however, so energy-intensive procedures using high temperatures, from 800 to 1400 F, or strong chemicals are needed to break down and recycle them. Previous studies have shown that noble metals, such as zirconium, platinum and ruthenium, can catalyze the process of splitting apart short, simple hydrocarbon chains and complicated, plant-based lignin molecules at moderate reaction temperatures requiring less energy than other techniques. So, Yuriy Román-Leshkov and colleagues wanted to see if metal-based catalysts would have a similar effect on solid polyolefins with long hydrocarbon chains, disintegrating them into usable chemicals and natural gas.
The researchers developed a method to react simple hydrocarbon chains with hydrogen in the presence of noble- or transition-metal nanoparticles under mild conditions. In their experiments, ruthenium-carbon nanoparticles converted over 90% of the hydrocarbons into shorter compounds at 392 F. Then, the team tested the new method on more complex polyolefins, including a commercially available plastic bottle. Despite not pretreating the samples, as is necessary with current energy-intensive methods, they were completely broken down into gaseous and liquid products using this new method. In contrast to current degradation methods, the reaction could be tuned so that it yielded either natural gas or a combination of natural gas and liquid alkanes. The researchers say implementing their method could help reduce the volume of post-consumer waste in landfills by recycling plastics to desirable, highly valuable alkanes, though technology to purify the products is needed to make the process economically feasible.
The authors acknowledge funding from the U.S. Department of Energy’s ,ÌýÌý²¹²Ô»åÌý.
###
The American Chemical Öйú365betÖÐÎĹÙÍø (ACS) is a nonprofit organization founded in 1876 and chartered by the U.S. Congress. ACS is committed to improving all lives through the transforming power of chemistry. Its mission is to advance scientific knowledge, empower a global community and champion scientific integrity, and its vision is a world built on science. The Öйú365betÖÐÎĹÙÍø is a global leader in promoting excellence in science education and providing access to chemistry-related information and research through its multiple research solutions, peer-reviewed journals, scientific conferences, e-books and weekly news periodical Chemical & Engineering News. ACS journals are among the most cited, most trusted and most read within the scientific literature; however, ACS itself does not conduct chemical research. As a leader in scientific information solutions, its CAS division partners with global innovators to accelerate breakthroughs by curating, connecting and analyzing the world’s scientific knowledge. ACSâ€� main offices are in Washington, D.C., and Columbus, Ohio.
Registered journalists can subscribe to the to access embargoed and public science press releases. For media inquiries, contact newsroom@acs.org.
Note: ACS does not conduct research but publishes and publicizes peer-reviewed scientific studies.
Media Contact
ACS Newsroom
newsroom@acs.org
###
La sociedad American Chemical Öйú365betÖÐÎĹÙÍø (ACS) es una organización sin fines de lucro fundada en 1876 y aprobada por el Congreso de los Estados Unidos. La ACS se ha comprometido a mejorar la vida de todas las personas mediante la transformación del poder de la quÃmica. Su misión es promover el conocimiento cientÃfico, empoderar a la comunidad global y defender la integridad cientÃfica, y su visión es un mundo construido basándose en la ciencia. La Sociedad es lÃder mundial en la promoción de la excelencia en la educación cientÃfica y en el acceso a información e investigación relacionadas con la quÃmica a través de sus múltiples soluciones de investigación, publicaciones revisadas por expertos, conferencias cientÃficas, libros electrónicos y noticias semanales periódicas de Chemical & Engineering News. Las revistas de la ACS se encuentran entre las más citadas, las más fiables y las más leÃdas en la literatura cientÃfica; sin embargo, la propia ACS no realiza investigación quÃmica. Como lÃder en soluciones de información cientÃfica, su división CAS se asocia con innovadores internacionales para acelerar los avances mediante la preservación, la conexión y el análisis de los conocimientos cientÃficos del mundo. Las sedes principales de la ACS se encuentran en Washington, D.C., y Columbus, Ohio.
Los periodistas registrados pueden suscribirse al en EurekAlert! para acceder a comunicados de prensa públicos y retenidos. Para consultas de los medios, comunÃquese con newsroom@acs.org.
Nota: ACS no realiza investigaciones, pero publica y divulga estudios cientÃficos revisados por expertos.â€�
;void(0);){kind=link}